Daniel married Anna Christina Louisa Vahl. Anna (daughter of Otto Martin Vahl and Dorothea Maria Haeger) was born 9 Feb 1809, Klein Panknin, Belgard, Pommern; died 8 Nov 1856, Belgard, Pommern; was buried 11 Nov 1856. [Group Sheet]

1. Hermann Daniel Albert Polzin was born 7 Dec 1829, Rostin, Belgard, Pommern.
2. Georg Ernst Gottfried Polzin was born 25 Nov 1831, Rostin, Belgard, Pommern; died 11 Dec 1831, Rostin, Belgard, Pommern.
3. Henriette Wilhelmine Christine Polzin was born 5 Mar 1834, Rostin, Belgard, Pommern.